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Volume # 1(20), January - February 2002 — "New approach to the functional trifluoropropane compounds"

Fluorine Notes, 2002, 20, 5-6

NEW APPROACH TO THE FUNCTIONAL TRIFLUOROPROPANE COMPOUNDS

S. Igumnov, K. Narinian, E. Igurrmova, A. Gontar

Addition of freones to the fluoroalkenes is an adequate method of synthesizing of the different aliphatic fluorine compounds [1].

Reactions of CH2FCl and CFCI3 with 1,1-difluoroethene were studied with the purpose of searching the new approaches of synthesizing trifluoropropionic acid, trifluoropropanol and the analogous compounds.

It is found that freones 11 and 21 under pressure at the room temperature are added to CF2=CH2 having good yield.

 

 

As a result Trifluoropropanes (I, II) being formed are easily converted to trifluoropropanol, trifluoropropene and trifluoropropionic acid.

1. W.A. Sheppard, C.M. Sharts . Organic Fluorine Chemistry [ Russian Translation], Mir, Moscow. 1972 p. 272

Fluorine Notes, 2002, 20, 5-6

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