FLUORINE CONTAINING POLYMER MATERIALS BASED ON UNSATURATED ACIDS MODIFIED ACCORDING TO ESTER FRAGMENT AND THEIR PRACTICAL APPLICATION
 

V.B. No ^a,  G.G. Furin ^b

^a  PIKO Enterprise LLC , 8 Galterina str., Perm City Russia 614113.

^b  Novosibirsk Institute of Organic Chemistry named after N.N. Vorojtsov SD of RAS,  9 Academic Lavtrentiev avenue, Novosibirsk, 630090, Russia E-mail : furin@nioch.nsc.ru

     Here we discuss the approach to the fluorine modification of acrylates and maleates ester fragment using partly fluorinated alcohols and acrylic, methacrylic and maleic acids' derivatives to synthesize them. We also discuss the reactions involving multiply bond and carboxylic group of maleic acid fluorine containing mono-ester and acrylic acid esters.  We analyze acrylates polymerization processes their co-polymerization with other olefines,  and also fluorine containing polymers' characteristics. We also take a look at practical application fields of such polymer materials. 

Contents

      Introduction.

1. Approaches of fluorine modified ester fragment acrylates synthesis.

2. Maleic acid fluorine containing mono- and diesters obtaining.

3. The synthesis of sulfoacids derivatives based on fluorine containing acrylic and maleic acids esters and their salts. 

4. Polymerization and co-polymerization of fluorine containing acrylates.

5. Practical application fields of fluorine containing polymer materials based on fluorinated acrylates and maleates.