THE SYNTHESIS AND SOME CHARACTERISTICS OF PARTLY FLUORINATED ALCOHOLS ON THE BASIS OF TETRAFLUOROETHYLENE AND HEXAFLUOROPROPYLENE 
(REVIEW)

G.G. Furin 

The Organic Chemistry Institute named after N.N. Vorojtzov of the Novosibirsk city Sibirian department of Russian Academy of Sciences 
9, Academic Ak. Lavrentiev avenue, Novosibirsk, 6300090 Russia 
E-mail : furin@nioch.nsc.ru

In this review the approaches of partly fluorinated alcohols on the tetrafluoroethylene and hexafluoropropylene basis are analyzed. New experimental data regarding telomeric alcohols involvement into reactions with unsaturated compounds  and hetero-organic derivatives are discussed. Oxidization processes and reactions in strong acid mediums of telomeric alcohols are analyzed. Also in this review you will find the trends of practical using of telomeric alcohols. The questions regarding partly fluorinated alcohols toxicity and some of their derivatives are discussed here. 

Table of contents

Introduction. The role of fluorine containing compounds in new fluorine materials creation. 

1. The development of partly fluorinated alcohols obtaining technology using interaction of teterafluoroethylene and hexafluoropropylene with alcohols in the presence of radical initiators.

2. Partly fluorinated alcohols as effective O-nucleophilic reagents, their application for creating of fluorine containing semi-products and materials on their basis. 

2.1. The interaction of trimethylsilyl ethers of partly fluorinated alcohols with unsaturated compounds – the synthesis way of wide application field dialkyl ethers.

2.2. The reactions of polyfluoroaromatic compounds with telomeric alcohols and creating of new materials on their basis. 

2.3. The interaction of telomeric alcohols with hetero-organic compounds.

2.4. The oxidization of telomeric alcohols till polyfluorinated carboxylic acids and their (acids) practical use.

2.5. Dielectric heat-transfers synthesis on the base of partly fluorinated alcohols.

2.6. The processes with telomeric alcohols participation. 

3. The toxicity of partly fluorinated alcohols and some derivatives.

References