The electrolytic method of fluorination in the medium containing the complexes of anhydrous hydrogen fluoride and trialkylamines.G.G.Furin Novosibirsk Institute of organic chemistry named after N.N.Vorozhtsov ABSTRACT The review generalizes and systematizes the latest date on fluorination of the various classes of organic compounds by the electrolytic anodic oxidation method in the medium of electrolyte – the complexes of anhydrous hydrogen fluoride and
trialkylamines. An analysis was performed of the basic achievements of the method of one atom fluorine introduction. The facts having an influence on the process and influence of electron-seeking substitutes arranged by CH-fragment and by heteroatoms of VIA group are shown. The examples are given of the useful applications of this method for the synthesis of aromatic and heterocyclic compounds as well as compounds having XCHF fragments, where X=S, Se, Te, as the potential intermediate products for synthesis of the preparations possessing a biological activity. The new efficient production methods of monofluorine – containing organic compounds and their role in organic synthesis are discussed. Contents Introduction
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