INTERNAL PERFLUOROOLEFINS IN A SYNTHESIS OF FLUOROORGANIC COMPOUNDS

G.G. FURIN

Institute of Organic Chemistry, 630090, Novosibirsk, Russia

Abstract

CONTENTS

1. Introduction

2. Synthesis of partially fluorinated organic compounds using the reaction of internal perfluoroolefins with nucleophilic reagents.

2.1. The interaction of internal perfluoroolefins with O-nucleophilic reagents in the synthesis of fluoroorganic materials and intermediate products.

2.2. The reaction of S-nucleophiles with internal perfluoroolefins.

2.3. The specific interaction of N-nucleophilic reagents with the internal perfluoroolefins containing fluorine atoms on a carbon-carcon double bond.

2.4. Fluoride ion as a catalyst in generating C-nucleophile from perfluoroolefins and its interaction with electrophiles. NEW!

2.5. Izomerization of internal perfluoroolefines.

3. Synthesis of perfluorinated compounds internal perfluoro-olefins and elementary fluorine.

3.1. New approach to generate superstable radicals and their reactions with internal perfluoroolefins and elementary fluorine.

3.2. Other methods to generate stable radicals and problems stability and reactivity perfluoroalkyl radicals.

4. Conclusion

References.

Index