Conclusion. The above-mentioned material allows to ascertain the growing interest of the researchers to the new approaches of introduction of perfluorinatered fragments to organic molecules and transformations of the simple substituents to complex functional groups. The significant successes achieved in development of methods, which help to carry out the introduction of fluorocontaining fragments to organic molecules. It is necessary to note that was studied the reactions of wide using internal perfluoroolefins with fluoride-ion. Such processes have advantages and can give the real opportunities of application in industrial technologies. It is expected that realization of this methodology help to open the new reactions and transformations resulting the synthesis of fluorocontaining compounds. Taking into account all above-mentioned, in the review we basically try to show the new approaches, opportunities of new reagents and new ideas, which are realized in the organic synthesis. Besides we aspired to show the tendencies and basic directions of researches in the field of a synthesis of perfluorocontaining organic substances containing a various molecular skeleton and functional groups. Certainly questions concerning the realization of these ideas and processes are attractive not only for the chemists working in field of fluoroorganic compounds, but also for experts of organic synthesis. Thus, perfluoroorganic compound in number moments are convenient, and moreover sometimes they are the unique models for decision of a number fundamental questions of theoretical organic chemistry.
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